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- Title
Al<sub>2</sub>O<sub>3</sub>‐coated BiVO<sub>4</sub> Photoanodes for Photoelectrocatalytic Regioselective C−H Activation of Aromatic Amines.
- Authors
Wang, Jinghao; Zuo, Lulu; Guo, Zhiyu; Yang, Caoyu; Jiang, Yuheng; Huang, Xuewei; Wu, Lizhu; Tang, Zhiyong
- Abstract
Photoelectrochemistry is becoming an innovative approach to organic synthesis. Generally, the current photoelectrocatalytic organic transformations suffer from limited reaction type, low conversion efficiency and poor stability. Herein, we develop efficient and stable photoelectrode materials using metal oxide protective layer, with a focus on achieving regioselective activation of amine compounds. Notably, our photoelectrochemistry process is implemented under mild reaction conditions and does not involve any directing groups, transition metals or oxidants. The results demonstrate that beyond photocatalysis and electrocatalysis, photoelectrocatalysis exhibits high efficiency, remarkable repeatability and good functional group tolerance, highlighting its great potential for applications.
- Subjects
AROMATIC amines; TRANSITION metals; PHOTOELECTROCHEMISTRY; FUNCTIONAL groups; ELECTROCATALYSIS
- Publication
Angewandte Chemie, 2023, Vol 135, Issue 52, p1
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.202315478