We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Use of Unprecedented Intramolecular 1, 3‐Dipolar Cycloaddition Reaction in meso‐Nitrile Oxide‐Containing BODIPYs as a New Pathway for the Preparation of Fused NIR Platforms.
- Authors
Zatsikha, Yuriy V.; Prasannan, Dijo; Scharge, Briana; Herbert, David E.; Gerasimchuk, Nikolay N.; Zeller, Mattias; Nemykin, Victor N.
- Abstract
Meso‐nitrile oxide group in 1,7‐Diphenyl‐containing BODIPYs can be involved in highly unusual [3+2] intramolecular cycloaddition reaction with the formation of the dihydrobenzo[d]isoxazole‐containing BODIPYs. Oxidation of these compounds results in the formation of unprecedented either benzisoxazole‐ or benzo[b]azepine‐fused fully conjugated NIR absorbing BODIPYs. The photophysical properties and electronic structures of the target compounds were studied by an array of experimental and theoretical methods.
- Subjects
ELECTRONIC structure; NITRILE oxides; RING formation (Chemistry); ISOXAZOLES; OXIDATION
- Publication
Chemistry - A European Journal, 2024, Vol 30, Issue 35, p1
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.202401210