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- Title
Synthesis of Hypervalent Iodine Diazo Compounds and Their Application in Organic Synthesis.
- Authors
Zhang, Cai; Wan, Jie‐Ping
- Abstract
Diazomethyl‐substituted iodine(III) compounds with electron‐withdrawing groups (EWG) connected to diazo methyl center were a type of donor‐acceptor diazo compounds with potential reaction abilities similar to ordinary diazo compounds. Although several diazomethyl‐substituted iodine(III) compounds were synthesized and used in the nucleophilic substitution reactions as early as 1994, the synthesis and application of new iodine(III) diazo compounds have only been reported to a certain extent in recent years. In the presence of rhodium catalyst, photocatalyst, or nucleophiles, diazomethyl‐substituted iodine(III) compounds can be converted into rhodium‐carbenes, diazomethyl radicals, ester radicals or nucleophilic intermediates, which can be used as key intermediates for the formation of chemical bonds. The aim of this review is to give an overview of diazomethyl‐substituted iodine(III) compounds in organic synthesis.
- Subjects
IODINE compounds; DIAZO compounds; NUCLEOPHILIC substitution reactions; ORGANIC synthesis; RHODIUM catalysts; SUBSTITUTION reactions; RADICALS (Chemistry); CHEMICAL bonds
- Publication
Chemistry - A European Journal, 2024, Vol 30, Issue 5, p1
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.202302718