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- Title
Identifying crystallographic faces of the fluorites urania and thoria with rotational polarized Raman spectroscopy.
- Authors
Morgan, Phyllis K.; Prusnick, Timothy A.; Velez, Michael A.; Rickert, Karl; Turner, David B.; Mann, James Matthew
- Abstract
Crystallite orientation identification is invaluable, but is often limited to small area identification or requires a large area sample. Nondestructive optical methods such as polarized Raman spectroscopy, in contrast, can be used to completely map a variety of sample sizes, but their potential is not yet fully realized. Here, we report a systematic study of polarized Raman scattering of high‐quality, hydrothermally grown, single crystals of urania and thoria. The peak intensity variations for as‐grown major crystal planes, post‐growth polished crystal planes, and a post‐growth polished non‐crystallographic plane are directly linked to crystallographic orientation and crystal rotation, and agree with computed models. In particular, the parallel polarized peak intensity results are directly correlated with metal–oxygen–metal chains in the fluorite structure and can be used to determine both orientation and rotational alignment of a given crystal face if sufficiently small rotational steps are applied. These results are structure based, being applicable to the larger fluorite phase space, which is useful for optical, semiconductor, nuclear, and solid oxide fuel cell industries. Further, these results suggest that Raman spectroscopy can identify non‐crystallographic orientations that are not discernable by traditional means.
- Subjects
RAMAN spectroscopy; THORIUM dioxide; SOLID oxide fuel cells; FLUORITE; FUEL cell industry; CRYSTAL orientation
- Publication
Journal of Raman Spectroscopy, 2021, Vol 52, Issue 11, p1902
- ISSN
0377-0486
- Publication type
Article
- DOI
10.1002/jrs.6236