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- Title
Allylation of Orthoquinones Towards Annulated Polycyclic Aromatic Systems.
- Authors
Kędziorek, Mariusz; Dobrzańska, Liliana
- Abstract
Promising results of an efficient and convenient strategy for the annulation of polycyclic aromatic compounds (PACs), employing orthoquinones as starting material and comprising allylation, pinacol rearrangement, ring-closing metathesis (RCM), and one-pot reduction followed by Wagner-Meerwein rearrangement, are presented. The strategy involves introducing triallylborane prepared in situ in the allylation step. Moreover, a novel expedient method for the preparation of 9,10-diallylphenanthrene was introduced.
- Subjects
ALLYLATION kinetics; POLYCYCLIC aromatic compounds; PINACOL rearrangement; METATHESIS reactions; LIGHT emitting diodes
- Publication
Molecules, 2018, Vol 23, Issue 8, p2043
- ISSN
1420-3049
- Publication type
Article
- DOI
10.3390/molecules23082043