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- Title
Ising-like Magnetism in Quasi-Two-Dimensional Co(NO 3) 2 ·2H 2 O.
- Authors
Vorobyova, Anna A.; Danilovich, Igor L.; Morozov, Igor V.; Vasiliev, Alexander N.; Volkova, Olga S.; Iqbal, Asif; Rahaman, Badiur; Saha-Dasgupta, Tanusri
- Abstract
The appearance of electrically neutral water molecules in the structure of cobalt dinitrate dihydrate, Co(NO3)2⋅2H2O, drastically changes its magnetic properties as compared to its waterless counterpart, Co(NO3)2. The title compound shows Ising-like behavior reflected in its thermodynamic properties. It experiences long-range antiferromagnetic order at TN = 20.5 K and metamagnetic transition at µ0HC = 0.76 T. First-principles calculations produce the values of leading exchange interactions J1 ~ 10 K and J2 ~ 0.5 K and single-ion anisotropy D ~ 1 K which allows us to consider Co(NO3)2⋅2H2O as a quasi-two-dimensional magnetic system.
- Subjects
THERMODYNAMICS; MAGNETISM; MAGNETIC properties; METAMAGNETISM; COBALT; LABOR theory of value; ANTIFERROMAGNETIC materials
- Publication
Materials (1996-1944), 2022, Vol 15, Issue 20, p7066
- ISSN
1996-1944
- Publication type
Article
- DOI
10.3390/ma15207066