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- Title
Facile Synthesis of Brush Poly(phosphoamidate)s via One-Pot Tandem Ring-Opening Metathesis Polymerization and Atom Transfer Radical Polymerization.
- Authors
Ding, Liang; Qiu, Jun; Wei, Jun; Zhu, Zhenshu
- Abstract
Poly(2-(dimethylamino)ethyl methacrylate) (PDMAEMA)-based brush poly(phosphoamidate)s are successfully synthesized by a combination of ring-opening metathesis polymerization (ROMP) and atom transfer radical polymerization (ATRP) following either a commutative two-step procedure or a straightforward one-pot process using Grubbs ruthenium-based catalysts for tandem catalysis. Compared with the traditional polymerization method, combining ROMP and ATRP in a one-pot process allows the preparation of brush copolymers characterized by a relatively moderate molecular weight distribution and quantitative conversion of monomer. Moreover, the surface morphologies and aggregation behaviors of these polymers are studied by AFM and TEM measurements.
- Subjects
METATHESIS reactions; POLYMERIZATION research; ATOM transfer reactions; POLYMETHYLMETHACRYLATE; RING-opening polymerization
- Publication
Macromolecular Rapid Communications, 2014, Vol 35, Issue 17, p1509
- ISSN
1022-1336
- Publication type
Article
- DOI
10.1002/marc.201400050