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- Title
Living Anionic Polymerization of tert-Butyl Acrylate in a Flow Microreactor System and Its Applications to the Synthesis of Block Copolymers.
- Authors
Nagaki, Aiichiro; Takahashi, Yusuke; Akahori, Kana; Yoshida, Jun-ichi
- Abstract
Living anionic polymerization of tert-butyl acrylate initiated by 1,1-diphenylhexyllithium is conducted in a flow microreactor system in the presence of lithium chloride. A high degree of control over the molecular weight distribution is achieved under easily accessible conditions, for example at −20 °C. The subsequent reaction of a reactive polymer chain end with an alkyl methacrylate in an integrated flow micoreactor system leads to the formation of a block copolymer with a narrow molecular weight distribution.
- Publication
Macromolecular Reaction Engineering, 2012, Vol 6, Issue 11, p467
- ISSN
1862-832X
- Publication type
Article
- DOI
10.1002/mren.201200051