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- Title
[6-(Thiophen-2-yl)-2,2′-bipyridine]bis(triphenylphosphine) Copper(I) Tetrafluoroborate.
- Authors
Kouvatsis, Panagiotis; Glykos, Dimitrios; Plakatouras, John C.; Malandrinos, Gerasimos
- Abstract
The novel heteroleptic copper (I) complex [6-(thiophen-2-yl)-2,2′-bipyridine]bis(triphenylphosphine) copper(I) tetrafluoroborate (1), formulated as [CuL(PPh3)2]BF4, was synthesized in two steps, utilizing the diimine type ligand L = 6-(thiophen-2-yl)-2,2′-bipyridine and triphenylphosphine (PPh3). The compound was characterized both in the solid state and in solution by employing single crystal X-ray diffraction, IR, UV, and NMR spectroscopies. The complex is an orange emitter that demonstrates a photoluminescence quantum yield of 2.6% in the solid state.
- Subjects
TETRAFLUOROBORATES; TRIPHENYLPHOSPHINE; COPPER; X-ray diffraction; SINGLE crystals
- Publication
Molbank, 2023, Vol 2023, Issue 1, pM1605
- ISSN
1422-8599
- Publication type
Article
- DOI
10.3390/M1605