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- Title
Palladium-Ruthenium Catalyst for Selective Hydrogenation of Furfural to Cyclopentanol.
- Authors
Mironenko, R. M.; Belskaya, O. B.; Lavrenov, A. V.; Likholobov, V. A.
- Abstract
Bimetallic Pd-Ru/C catalyst was shown to be much more active in the aqueous-phase hydrogenation of furfural (473 K, 8 MPa) in comparison with both Pd/C and Ru/C catalysts. The enhanced hydrogenation activity manifested itself as an increased yield of cyclopentanol (77%) at a complete conversion of furfural. The observed synergistic effect between palladium and ruthenium in the tested reaction can be related to changes in the electronic state and particle size of supported metals upon interaction with each other and the Pd-Ru alloy formation.
- Subjects
PALLADIUM catalysts; HYDROGENATION; PENTANOL; CATALYST supports; CHEMICAL yield
- Publication
Kinetics & Catalysis, 2018, Vol 59, Issue 3, p339
- ISSN
0023-1584
- Publication type
Article
- DOI
10.1134/S0023158418030151