We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
CO oxidation with oxygen of the catalyst and gas-phase oxygen over (0.5−15)%СоО/СеО.
- Authors
Il'ichev, N.; Fattakhova, Z.; Shashkin, D.; Matyshak, V.; Korchak, V.
- Abstract
The CO adsorption species on CoO and (0.5-15%)CoO/CeO catalysts have been investigated by temperature-programmed desorption and IR spectroscopy. At 20°C, the largest amount of CO is adsorbed on the 5%CoO/CeO sample to form, on Co O clusters, hydrogen-containing, bidentate, and monodentate carbonate complexes, whose decomposition is accompanied by CO desorption at 300 and 450°C (1.1 × 10 g). The formation of the carbonates is accompanied by the formation of Co cations and Co, on which carbonyls form. The latter decompose at 20, 90, and 170°C to release CO (2.7 × 10 g). Part of the carbonyls oxidizes to CO upon oxygen adsorption, and the CO undergoes desorption at 20°C. Adsorbed oxygen decreases the decomposition temperature of the H-containing and bidentate carbonates from 300 to 100-170°C and maintains the sample in the oxidized state, which is active in subsequent CO adsorption and oxidation. CO oxidation by oxygen of the catalyst diminishes the activity of the sample in these processes and increases the decomposition temperature of the carbonate complexes. Taking into account the properties of the adsorption complexes, we concluded that the H-containing and bidentate carbonates are involved in CO oxidation by oxygen of the catalyst at ~170°C under isothermal conditions. The rate limiting step is the decomposition of the carbonates, a process whose activation energy is 65-74 kJ/mol.
- Subjects
OXIDATION of carbon monoxide; OXYGEN; GAS phase reactions; ADSORPTION (Chemistry); TEMPERATURE effect; DESORPTION
- Publication
Kinetics & Catalysis, 2016, Vol 57, Issue 5, p686
- ISSN
0023-1584
- Publication type
Article
- DOI
10.1134/S0023158416050104