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- Title
Hydrogen‐Bonding‐Network‐Assisted Regioselective Trifluoromethylthiolation and Sulfenylation of Electron‐Rich (Hetero)arenes.
- Authors
Liu, Shiwen; Zeng, Xiaojun; Xu, Bo
- Abstract
We have developed an efficient and straightforward hydrogen‐bonding‐network‐assisted regioselective sulfenylation and trifluoromethylthiolation of electron‐rich arenes using the electrophilic SCF3 reagent and N‐thiosuccinimides. This catalyst‐free protocol offers good yields for a wide range of arenes and shows good functional group tolerance without any protecting groups.
- Subjects
ELECTROPHILES; REGIOSELECTIVITY (Chemistry); AROMATIC compounds; FUNCTIONAL groups; HYDROGEN bonding
- Publication
Asian Journal of Organic Chemistry, 2019, Vol 8, Issue 8, p1372
- ISSN
2193-5807
- Publication type
Article
- DOI
10.1002/ajoc.201900358