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- Title
Cobalt-Catalyzed Reductive Cross-Coupling Between Benzyl Chlorides and Aryl Halides.
- Authors
Pal, Suman; Chowdhury, Sushobhan; Rozwadowski, Elodie; Auffrant, Audrey; Gosmini, Corinne
- Abstract
A new protocol for the direct reductive cobalt-catalyzed arylation of benzyl chlorides has been developed in order to form functionalized diarylmethanes. A variety of reactive groups either on the aryl or the benzyl halide was employed. This represents the first cobalt-catalyzed reductive cross-coupling which does not require any ligand and pyridine. A reaction pathway is proposed involving a radical benzyl species.
- Subjects
ARYL halides; BENZYL halides; COBALT; METHANESULFONATES; DIARYL compounds
- Publication
Advanced Synthesis & Catalysis, 2016, Vol 358, Issue 15, p2431
- ISSN
1615-4150
- Publication type
Article
- DOI
10.1002/adsc.201600378