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- Title
Synthesis of [ReX(CO)] ( X = Cl, Br, and I).
- Authors
Miroslavov, A.; Alekseev, I.; Tyupina, M.; Lumpov, A.; Stepanova, E.; Kol'tsov, V.; Sidorenko, G.
- Abstract
Radiochemically pure [ReX(CO)] ( X = Cl, Br, and I) were prepared for the first time by high-pressure carbonylation of ReO with carbon monoxide in an aqueous solution in the presence of halide ions at 210 °C. The complexes were isolated at the n.c.a. level from the reaction mixture by gas-phase transport with carbon monoxide at a high pressure. The procedure allows obtaining the target compounds in any appropriate solvent (aqueous and nonaqueous), which may open new synthetic prospects for the development of novel therapeutic radiopharmaceuticals.
- Subjects
RHENIUM compounds synthesis; RADIOPHARMACEUTICALS; CARBONYLATION; CARBON monoxide; GAS phase reactions; AQUEOUS solutions
- Publication
Journal of Radioanalytical & Nuclear Chemistry, 2016, Vol 308, Issue 3, p1039
- ISSN
0236-5731
- Publication type
Article
- DOI
10.1007/s10967-015-4558-7