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- Title
After 200 Years: The Structure of Bleach and Characterization of Hypohalite Ions by Single‐Crystal X‐Ray Diffraction**.
- Authors
Topić, Filip; Marrett, Joseph M.; Borchers, Tristan H.; Titi, Hatem M.; Barrett, Christopher J.; Friščić, Tomislav
- Abstract
We report the first X‐ray single crystal structures of hypochlorite (ClO−) and hypobromite (BrO−) salts, including hydrated sodium hypochlorite, a staple of the chlorine industry and ubiquitous bleaching and disinfection agent for almost 200 years. The structures, supported by variable‐temperature Raman spectroscopy on individual crystals and periodic density‐functional theory (DFT) calculations, provide insight into solid‐state geometry and supramolecular chemistry of hypohalite ions.
- Subjects
X-rays; CRYSTAL structure; SINGLE crystals; SUPRAMOLECULAR chemistry; IONS
- Publication
Angewandte Chemie, 2021, Vol 133, Issue 46, p24605
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.202108843