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- Title
Catalytic System for Cross-Coupling of Heteroaryl Iodides with a Nitronyl Nitroxide Gold Derivative at Room Temperature.
- Authors
Zayakin, Igor; Romanenko, Galina; Bagryanskaya, Irina; Ugrak, Bogdan; Fedin, Matvey; Tretyakov, Evgeny
- Abstract
A simple and highly effective methodology for the cross-coupling of heteroaryl iodides with NN–AuPPh3 at room temperature is reported. The protocol is based on a novel catalytic system consisting of Pd2(dba)3·CHCl3 and the phosphine ligand MeCgPPh having an adamantane-like framework. The present protocol was found to be well compatible with various heteroaryl iodides, thus opening new horizons in directed synthesis of functionalized nitronyl nitroxides and high-spin molecules.
- Subjects
IODIDES; NITROXIDES; ADAMANTANE derivatives; GOLD; GOLD compounds; TEMPERATURE; ORGANIC compounds
- Publication
Molecules, 2023, Vol 28, Issue 22, p7661
- ISSN
1420-3049
- Publication type
Article
- DOI
10.3390/molecules28227661