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- Title
Ruthenium-Catalyzed Dehydrogenative Intermolecular O-H/Si-H/C-H Silylation: Synthesis of (E)-Alkenyl Silyl-Ether and Silyl-Ether Heterocycle.
- Authors
Huang, Ziwei; Lin, Qiao; Li, Jiefang; Xu, Shanshan; Lv, Shaohuan; Xie, Feng; Wang, Jun; Li, Bin
- Abstract
Selective dehydrogenative silylation is one of the most valuable tools for synthesizing organosilicon compounds. In this study, a regio- and stereoselective ruthenium-catalyzed dehydrogenative intermolecular silylation was firstly developed to access (E)-alkenyl silyl-ether derivatives and silyl-ether heterocycles with good functional group tolerance. Furthermore, two pathways for RuH2(CO)(PPh3)3/NBE-catalyzed dehydrogenative intermolecular silylation of alcohols and alkenes as well as intermolecular silylation of naphthol derivatives were investigated with H2SiEt2 as the hydrosilane reagent.
- Subjects
SILYLATION; SILYL ethers; ORGANOSILICON compounds; SILANE; NAPHTHOL; FUNCTIONAL groups
- Publication
Molecules, 2023, Vol 28, Issue 20, p7186
- ISSN
1420-3049
- Publication type
Article
- DOI
10.3390/molecules28207186