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- Title
Kinetic Investigation Exploiting Local Parameter Subset Selection: Isomerization of 1-Decene using a Rh-Biphephos Catalyst.
- Authors
Jörke, Andreas; Triemer, Susann; Seidel-Morgenstern, Andreas; Hamel, Christof
- Abstract
A kinetic study of the isomerization of 1-decene using a Rh-Biphephos catalyst was performed in order to parameterize a mechanistic kinetic model to observed experimental data. For the derivation of the kinetic model, a previously proposed catalytic cycle was revised regarding the catalyst pre-equilibrium including the formation of inactive or non-selective Rh-species. In order to estimate the model parameters and to support model reduction, a method based on parameter subset selection was extended and applied. Using this approach, sensitive kinetic parameters were identified and determined for the reduced kinetic model.
- Subjects
ISOMERIZATION kinetics; SUBSET selection; RHODIUM catalyst selectivity; PARAMETER identification; RHODIUM
- Publication
Chemie Ingenieur Technik (CIT), 2015, Vol 87, Issue 6, p713
- ISSN
0009-286X
- Publication type
Article
- DOI
10.1002/cite.201400148