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- Title
Unusual Reaction of Sodium 1,6-Dioxo-2,4-alkadiene-3,4-diolates under Acid Hydrolysis Conditions.
- Authors
Mukovoz, P. P.; Slepukhin, P. A.; Ganebnykh, I. N.; El’tsov, O. S.; Danilova, E. A.
- Abstract
The reaction of sodium 1,6-dioxo-2,4-alkadiene-3,4-diolates with HCl solution afforded unexpected hydrolysis products, namely (2Z)-2-hydroxy-4-oxobut-2-enoic (2,4-dioxobutanoic) acid esters. The structural features of the synthesized compounds were discussed on the basis of IR, 1H NMR spectroscopy, mass spectrometry and X-ray diffraction analysis data.
- Subjects
HYDROLYSIS; HYDROCHLORIC acid; X-ray diffraction; OXALATES; HYDROXYL group
- Publication
Russian Journal of General Chemistry, 2018, Vol 88, Issue 10, p2039
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S107036321810002X