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- Title
Investigation of Kinetics of Coordination of meso-Nitro-Substituted Derivatives of 5-Phenyl-β-octaalkylporphine with Palladium Acetate.
- Authors
Ivanova, Yu. B.; Plotnikova, A. O.; Pukhovskaya, S. G.; Mamardashvili, N. Zh.
- Abstract
Kinetics of the formation reactions of palladium complexes of meso-nitro-substituted 5-phenyl-β- octaalkylporphine derivatives in the Pd(OAc)2-acetonitrile system at 303-323 K was studied by spectrophotometry. The kinetic parameters of the formation reaction of complexes of porphyrins under study with palladium and zinc previously prepared, as well as their corresponding fluorescence spectra, were subjected to a comparative analysis. The parameters of electron absorption spectra of all palladium porphyrinates obtained were determined.
- Subjects
PALLADIUM; PHENYL compounds; ACETATES; PORPHYRINS; FLUORESCENCE
- Publication
Russian Journal of General Chemistry, 2018, Vol 88, Issue 5, p973
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363218050237