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- Title
Redox reactions involving Ce cations and FeO anions and the synthesis of CeFeO· nHO nanolayers by the SILD method.
- Authors
Kuklo, L.; Tolstoy, V.
- Abstract
Conditions for the synthesis of nanolayers of cerium and iron binary oxides by the successive ionic layer deposition (SILD) method based on consecutive and repeated realization of redox reactions in a layer of adsorbed Ce cations and FeO anions on a substrate surface were considered. The synthesized layers were studied by scanning electron microscopy, X-ray spectral microanalysis, IR-Fourier and X-ray photoelectron spectroscopy, and also by X-ray diffraction methods. Under conditions of the synthesis layers of the hydrated amorphous oxide CeFeO· nHO containing Ce(IV) and Fe(III) atoms in the ratio 1.1 : 1.0 are formed on the surface.
- Subjects
OXIDE synthesis; IRON oxide synthesis; CERIUM; OXIDATION-reduction reaction; DOPING agents (Chemistry)
- Publication
Russian Journal of General Chemistry, 2016, Vol 86, Issue 1, p1
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363216010011