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- Title
Kinetics of acid-base interaction of octaphenyl-substituted tetraazaporphyrins with nitrogen-containing bases in a system benzene-dimethylsulfoxide.
- Authors
Petrov, O. A.; Chizhova, N. V.; Osipova, G. V.
- Abstract
Effect of dimethylsulfoxide additives on the kinetics of acid-base interaction of octaphenyl-substituted tetraazaporphyrins with nitrogen-containing bases in benzene is studied. A strong effect of the solvent on the process rate and activation parameters is revealed. The relation of the molecular structure of the interacting molecules to their reactivity is demonstrated.
- Subjects
DIMETHYL sulfoxide; ACID-base chemistry; MOLECULAR structure; MOLECULAR dynamics; REACTIVITY (Chemistry); BENZENE; SOLVENTS
- Publication
Russian Journal of General Chemistry, 2009, Vol 79, Issue 4, p839
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363209040264