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- Title
Platinum Group Metal Phosphides as Efficient Catalysts in Hydroprocessing and Syngas-Related Catalysis.
- Authors
Alvarado Rupflin, Luis; Boscagli, Chiara; Schunk, Stephan Andreas
- Abstract
Platinum group metal phosphides are reviewed as catalytic materials for hydroprocessing and syngas-related catalysis. Starting from synthetic procedures leading to highly disperse nano-particular compounds, their properties in the applications are discussed and compared with relevant benchmarks, if available. Regarding their mode of action, two confronting mechanistic scenarios are presented: (i) a cooperative scenario in which catalytic sites of different functionalities are active in hydroprocessing and (ii) single site catalysis, which appears to be the relevant mode of action in syngas-related catalysis and which occurs over "frustrated" active sites.
- Subjects
PLATINUM group; PHOSPHIDES; HYDROFORMYLATION
- Publication
Catalysts (2073-4344), 2018, Vol 8, Issue 3, p122
- ISSN
2073-4344
- Publication type
Article
- DOI
10.3390/catal8030122