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- Title
Investigation of Carbon Supported Nanostructured PtAu Alloy as Electrocatalyst for Direct Borohydride Fuel Cell.
- Authors
İyigün Karadağ, Ç.; Behmenyar, G.; Boyacı San, F. G.; Şener, T.
- Abstract
Carbon supported bimetallic PtAu electrocatalysts for sodium borohydride electrooxidation are prepared by a modified citrate stabilized NaBH4 reduction process at different pH and temperature values. The physical properties of the materials are characterized by X-ray diffraction spectroscopy, energy dispersive spectrometry, X-ray photoelectron spectroscopy and transmission electron microscopy. Nano sized electrocatalysts have narrow size distributions and are uniformly dispersed on the surface of carbon support. Electrochemical performances of catalysts for sodium borohydride electrooxidation are tested with 25 cm2 single fuel cell. The highest performance is obtained at a peak power density of 161 mW cm−2 with 20 wt. % PtAu/C catalyst of 7.03 nm. Impact of the fuel cell operation parameters including concentration of NaBH4, flow rates of oxidant and fuel, and fuel cell operation temperature are investigated. The best operation parameters are obtained at 1 M NaBH4 concentration, 3 cm3 min−1 NaBH4 flow rate, 0.2 dm3 min−1 oxygen flow rate and 65 °C fuel cell temperature.
- Subjects
SODIUM borohydride; CATALYST support testing; NANOSTRUCTURED materials testing; PLATINUM group catalysts; PLATINUM-silver alloys; PERFORMANCE of fuel cells; ELECTROCATALYSTS; ELECTROLYTIC oxidation
- Publication
Fuel Cells, 2015, Vol 15, Issue 2, p262
- ISSN
1615-6846
- Publication type
Article
- DOI
10.1002/fuce.201300060