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- Title
Selective synthesis of tricyclopentadiene from dicyclopentadiene with homogeneous Pd catalysts.
- Authors
Woo, Jeong Oh; Park, Jong ‐ Eun; Han, JeongSik; Kwon, Tae Soo; Kim, Yeong ‐ Joon; Son, Kyung ‐ sun
- Abstract
We explored a simple synthetic strategy with homogeneous palladium catalysts to afford a [2 + 2] isomer of tricyclopentadiene in good yield (up to 98% from cyclopentadiene and up to 78% from dicyclopentadiene) with high selectivity. The effects of a variety of palladium precursors, phosphorus ligands and acids were investigated to improve the productivity and selectivity of the tricyclopentadiene synthesis. The reaction conditions were evaluated and their effects on the product distribution were also discussed. Copyright © 2014 John Wiley & Sons, Ltd.
- Subjects
CHEMICAL synthesis; DICYCLOPENTADIENE; PALLADIUM catalysts; LIGANDS (Chemistry); ISOMERS; CHEMICAL precursors
- Publication
Applied Organometallic Chemistry, 2014, Vol 28, Issue 3, p151
- ISSN
0268-2605
- Publication type
Article
- DOI
10.1002/aoc.3102