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- Title
Visible‐Light Promoted Radical Fluoroalkylation of O‐ and N‐Substituted Alkenes.
- Authors
Levin, Vitalij V.; Dilman, Alexander D.
- Abstract
Interaction of enol ethers enol acetates, enamides and enamines with fluorinated reagents may be considered as a reliable method for the synthesis of organofluorine compounds. While classic nucleophile/electrophile substitution or addition mechanisms cannot be realized for coupling of these components, their intrinsic reactivities are revealed with the aid of photoredox catalysis. A combination of these electron donating and accepting components provides a perfect balance needed for individual redox steps, which in some cases may proceed even without a photocatalyst. The same electronic factors also support the key C,C‐bond forming event involving addition of fluorinated radical at the electron rich double bond.
- Subjects
RADICALS (Chemistry); ENAMINES; ORGANOFLUORINE compounds; ELECTROPHILES; ALKENES; SILYL enol ethers; ENOL ethers; DOUBLE bonds
- Publication
Chemical Record, 2023, Vol 23, Issue 9, p1
- ISSN
1527-8999
- Publication type
Article
- DOI
10.1002/tcr.202300038