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- Title
(W<sub>6</sub>I<sub>8</sub>)Cl<sub>4</sub> - A Basic Model Compound for Photophysically Active [(W<sub>6</sub>I<sub>8</sub>)L<sub>6</sub>]<sup>2-</sup> Clusters?
- Authors
Ströbele, Markus; Enseling, David; Jüstel, Thomas; Meyer, H.‐Jürgen
- Abstract
The heteroleptic cluster compound (W6I8)Cl4 was prepared by thermal conversion of the homoleptic clusters W6I12 and W6Cl12 at 700 °C to yield a bright yellow powder. The presence of the smaller chlorido ligands in apical positions of [(W6I8)Cl6]2- creates nearly spherically clusters showing thermal and chemical inertness. Photoluminescence studies revealed a strong red phosphorescence from excited spin-triplet states.
- Subjects
HETEROLEPTIC compounds; PHOTOLUMINESCENCE; CRYSTAL structure; MOLECULAR structure of ligands; PHOSPHORESCENCE
- Publication
Zeitschrift für Anorganische und Allgemeine Chemie, 2016, Vol 642, Issue 24, p1435
- ISSN
0044-2313
- Publication type
Article
- DOI
10.1002/zaac.201600316