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- Title
A Biomimetic Synthesis of Sacculatane Diterpenoids.
- Authors
Marina Grinco; Veaceslav Kulciţki; Nicon Ungur; Pavel 4;F. Vlad; Margherita Gavagnin; Francesco Castelluccio; Guido Cimino
- Abstract
The biomimetic synthesis of sacculatane-type epimeric compounds 14a and 14b is reported. The key synthetic step is the low-temperature superacidic cyclization of (all-E)-ω-acetoxygeranylgeraniol 12 obtained in nine steps from geranyllinalool (13). The 19-acetoxysacculata-7,17-dien-11-ol (14a) could be an important and convenient starting compound for the synthesis of other sacculatane diterpenoids.
- Subjects
BIOMIMETIC chemicals; BIOSYNTHESIS; DITERPENES; RING formation (Chemistry)
- Publication
Helvetica Chimica Acta, 2008, Vol 91, Issue 2, p249
- ISSN
0018-019X
- Publication type
Article
- DOI
10.1002/hlca.200890031