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- Title
Third order nonlinear optical properties of β enhanced PVDF based nanocomposite thin films.
- Authors
Viswanath, Pamarti; Rambhatla, Pranaya Vamsy; Sai Kiran, Posam; Muthukumar, V. Sai
- Abstract
PVDF based nanocomposite thin films have received great interest in energy harvesting, ferroelectric, pyroelectric and dielectric applications. In this novel study, we have exploited the electroactive β-phase (polar) formation in polyvinylidine fluoride–halloysite nanotube (PVDF–HNT) nanocomposite thin films fabricated by the spin coating technique for nonlinear optical applications. It was demonstrated that HNTs of different volume percentage loadings in the PVDF matrix were able to effectively nucleate PVDF in β (TTTT-all trans) conformation using X-ray diffraction and Infrared spectroscopy techniques. Closed aperture Z-scan measurements were performed for all the thin film samples with a CW laser as an excitation source at a wavelength of 632.8 nm. We observed a sign change in the nonlinear refractive index for PVDF. Nonlinear refractive index has a negative sign for pristine PVDF and a positive sign for HNT incorporated PVDF thin films. This anomalous behavior of change in the nonlinear refraction of PVDF is explained in our present work.
- Subjects
NONLINEAR optics; THIN films; OPTICAL properties; NONLINEAR optical techniques; NEGATIVE refraction; CONTINUOUS wave lasers
- Publication
Journal of Materials Science: Materials in Electronics, 2019, Vol 30, Issue 13, p12447
- ISSN
0957-4522
- Publication type
Article
- DOI
10.1007/s10854-019-01604-6