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- Title
Iron-Catalyzed 1,2-Addition of Perfluoroalkyl Iodides to Alkynes and Alkenes.
- Authors
Xu, Tao; Cheung, Chi Wai; Hu, Xile
- Abstract
Iron catalysis has been developed for the intermolecular 1,2-addition of perfluoroalkyl iodides to alkynes and alkenes. The catalysis has a wide substrate scope and high functional-group tolerance. A variety of perfluoroalkyl iodides including CF3I can be employed. The resulting perfluoroalkylated alkyl and alkenyl iodides can be further functionalized by cross-coupling reactions. This methodology provides a straightforward and streamlined access to perfluoroalkylated organic molecules.
- Subjects
IRON; IODIDES; ALKYNES; ALKENES; MOLECULAR shapes
- Publication
Angewandte Chemie International Edition, 2014, Vol 53, Issue 19, p4910
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201402511