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- Title
η<sup>5</sup>-Cyclopentadienyliron(II)-[14]Triphyrin(2.1.1) Sandwich Compounds: Synthesis, Characterization, and Stable Redox Interconversion.
- Authors
Xue, Zhaoli; Kuzuhara, Daiki; Ikeda, Shinya; Sakakibara, Yuka; Ohkubo, Kei; Aratani, Naoki; Okujima, Tetsuo; Uno, Hidemitsu; Fukuzumi, Shunichi; Yamada, Hiroko
- Abstract
A semiferrocene complex with a [14]triphyrin(2.1.1) (TriP) ligand has been synthesized. The structure and properties are characterized by X‐ray crystallographic analysis, UV/Vis spectroscopy, and variable‐temperature 1H NMR spectroscopy. The FeII and FeIII complexes are electrochemically reversible.
- Subjects
CYCLOPENTADIENE; RESEARCH; FERROCENE; ELECTRON donor-acceptor complexes; OXIDATION-reduction reaction; PHENYL group; CYCLIC voltammetry
- Publication
Angewandte Chemie International Edition, 2013, Vol 52, Issue 28, p7306
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201302815