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- Title
Heterogeneous equilibria in the system uranoborate M<sup>II</sup>(BUO<sub>5</sub>)<sub>2</sub> · nH<sub>2</sub>O-aqueous solution (M<sup>II</sup>=Mn, Co, Ni, Zn).
- Authors
Chernorukov, N.; Knyazev, A.; Khomyakova, V.; Nipruk, O.
- Abstract
Solutions of uranoborates MII(BUO5)2· nH2O (MII=Mn, Co, Ni, Zn) in aqueous mineral acids at 25°C are studied. Based on experimental data on the solubility of uranoborates in hydrochloric acid, a quantitative model of the system crystalline uranoborate-aqueous solution is suggested. The model is used to predict the state of the investigated heterogeneous systems under various conditions, and also to estimate the standard thermodynamic functions of the indicated series of uranoborates.
- Subjects
BORATES; HYDROCHLORIC acid; THERMODYNAMICS; QUANTITATIVE chemical analysis; PHYSICAL &; theoretical chemistry
- Publication
Radiochemistry, 2006, Vol 48, Issue 1, p18
- ISSN
1066-3622
- Publication type
Article
- DOI
10.1134/S106636220601005X