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- Title
Ruthenium NNN‐Based Pincer Complexes with Metal Ligand Cooperation as Catalysts for N‐Methylation of Anilines and Nitroarenes with Methanol as a C1 Source.
- Authors
Garg, Nitish K.; Goriya, Yogesh; Manojveer, Seetharaman; Wendt, Ola F.; Johnson, Magnus T.
- Abstract
A novel phosphine‐free ruthenium pincer complex based on an NNN pincer ligand has been prepared and fully characterized. The complex was subsequently employed as an efficient catalyst for the N‐methylation of amines and the direct N‐methylation of nitroarenes using methanol as a C1 source under mild reaction conditions following the borrowing‐hydrogen approach. Both of the catalytic transformations were performed with only catalytic amounts of base under closed air conditions without using any other additives.
- Subjects
LIGANDS (Chemistry); NITROAROMATIC compounds; RUTHENIUM; ANILINE; CATALYSTS; METAL complexes; RUTHENIUM catalysts; METHANOL as fuel
- Publication
ChemCatChem, 2024, Vol 16, Issue 12, p1
- ISSN
1867-3880
- Publication type
Article
- DOI
10.1002/cctc.202301601