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- Title
Formation of a Six-Coordinate fac-[Re(CO)<sub>3</sub>]<sup>+</sup> Complex by the N-C Bond Cleavage of a Potentially Tetradentate Ligand.
- Authors
Booysen, I.; Gerber, T. I. A.; Hosten, E.; Mayer, P.
- Abstract
The rhenium(I) compound fac-[Re(CO)3(daa)].Hpab.H2O (Hpab = N,N'-(1,2-phenylene)bis(2′-aminobenzamide); Hdaa = 2- amino-N-(2-aminophenyl)benzamide) was synthesized from the reaction of [Re(CO)5Br] with two equivalent of Hpab in toluene. The monoanionic tridentate ligand daa was formed by the rhenium-mediated cleavage of an amido N-C bond of the potentially tetradentate ligand Hpab. The compound was characterized by IR spectroscopy and X-ray crystallography, and daa is coordinated as a diaminoamide via three nitrogen-donor atoms.
- Subjects
LIGANDS (Chemistry); SCISSION (Chemistry); CRYSTALLOGRAPHY; COMPLEX compounds; CHEMICAL reactions; PHYSICAL &; theoretical chemistry; CHEMISTRY education
- Publication
Journal of the Iranian Chemical Society, 2008, Vol 5, Issue 4, p689
- ISSN
1735-207X
- Publication type
Article
- DOI
10.1007/BF03246150