We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Modeling of CO<sub>2</sub> equilibrium solubility in a novel 1-Diethylamino-2-Propanol Solvent.
- Authors
Liu, Helei; Xiao, Min; Luo, Xiao; Gao, Hongxia; Idem, Raphael; Tontiwachwuthikul, Paitoon; Liang, Zhiwu
- Abstract
In this work, the equilibrium solubility of CO2 in a 1-diethylamino-2-propanol (1DEA2P) solution was determined as a function of 1DEA2P concentration (over the range of 1-2 M), temperature (in the range of 298-333 K), and CO2 partial pressure (in the range of 8-101 kPa). These experimental results were used to fit the present correlation for K2 (Kent-Eisenberg model, Austgen model, and Li-Shen model). It was found that all of the models could represent the CO2 equilibrium solubility in 1DEA2P solution with ADDs for Kent-Eisenberg model, Austgen model, and Li-Shen model of 6.3, 7.3, and 12.2%, respectively. A new K2 correlation model, the Liu-Helei model, was also developed to predict the CO2 equilibrium solubility in 1DEA2P solution with an excellent ADD of 3.4%. In addition, the heat of absorption of CO2 in 1DEA2P solution estimated by using the Gibbs-Helmholtz equation was found to be −45.7 ± 3.7 kJ/mol. Information and guidelines about effectively using data for screened solvents is also provided based on the three absorption parameters: CO2 equilibrium solubility, second order reaction constant (k2), and CO2 absorption heat. © 2017 American Institute of Chemical Engineers AIChE J, 63: 4465-4475, 2017
- Subjects
CARBON dioxide solubility; PROPANOLS; STATISTICAL correlation; GIBBS-Helmholtz equation; SOLVENTS
- Publication
AIChE Journal, 2017, Vol 63, Issue 10, p4465
- ISSN
0001-1541
- Publication type
Article
- DOI
10.1002/aic.15797