We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
A Facile Preparation of N‐Heterocyclic Olefins: Ring‐Opening Polymerization of β‐Butyrolactone and Frustrated Lewis Pair Reactivity.
- Authors
Rajendran, Natesan Mannangatti; Lu, Qi; Bouffard, Jean
- Abstract
A direct synthesis of N‐heterocyclic olefins (NHOs) and their mesoionic congeners (mNHOs) from N‐heterocyclic carbenes and N‐aziridinylimines is reported. The reaction provided diverse functionalized (m)NHOs and π‐extended analogues. The prepared NHOs initiated the ring‐opening polymerization of β‐butyrolactone, and insertion of aldehyde and nitrile into an NHO‐B(C6F5)3 adduct was demonstrated.
- Subjects
LEWIS pairs (Chemistry); ALKENES; RING-opening polymerization; CARBENES; ALDEHYDES
- Publication
Chemistry - A European Journal, 2024, Vol 30, Issue 8, p1
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.202303358