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- Title
SYNTHESIS AND CATALYTIC PROPERTY OF A RARE EARTH COORDINATION POLYMER.
- Authors
YANG YUN; GONGFENG XU; SHI REN
- Abstract
Hydrothermal reactions of rare earth ions(III) with a flexible building unit (1,3,4-thiadiazole- 2,5-diyldithio) diacetic acid (H2tzda) lead to a novel coordination polymer namely, {[Y2(tzda)3(H2O)10]•5H2O}n. Furthermore, it is used to treat petrochemical wastewater in supercritical water in this paper. It showed good catalytic performance. TOC removal can be up to 95.2%. TOC removal increased by 25% when the quality of {[Y2(tzda)3(H2O)10]•5H2O}n is 3 g.
- Subjects
COORDINATION polymers synthesis; RARE earth metal compound synthesis; CATALYTIC activity; HYDROTHERMAL synthesis; THIADIAZOLES; ACETIC acid; SUPERCRITICAL water; PETROLEUM chemicals
- Publication
Oxidation Communications, 2016, Vol 39, Issue 3-II, p2513
- ISSN
0209-4541
- Publication type
Article