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- Title
Fluorescence Photoswitching in a Series of Metal‐Organic Frameworks Loaded with Different Anthracenes.
- Authors
Tu, Min; Díaz Ramírez, Mariana Lizeth; Ibarra, Ilich A.; Hofkens, Johan; Ameloot, Rob
- Abstract
The confinement of luminescent guest molecules in porous host materials can induce photophysical properties different from either component in isolation. In this work, we studied several host‐guest systems consisting of anthracene and its substituted analogs adsorbed in a series of metal‐organic frameworks (MOFs) and inorganic molecular sieves. Fluorescence photoswitching of the guest molecules through photoinduced dimerization is observed only in MOFs with a favorable pore volume and geometry.
- Subjects
ANTHRACENE; FLUORESCENCE; MOLECULAR sieves; POROUS materials; METAL-organic frameworks; DIMERIZATION
- Publication
European Journal of Inorganic Chemistry, 2021, Vol 2021, Issue 29, p2986
- ISSN
1434-1948
- Publication type
Article
- DOI
10.1002/ejic.202100415