We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Hydrosilylation of Alkenes Using a Hydrosiloxane as a Surrogate for Me<sub>2</sub>SiH<sub>2</sub> and Catalyzed by a Nickel‐Pincer Complex.
- Authors
Hashimoto, Toru; Shiota, Keisuke; Ishimaru, Toshiya; Yamaguchi, Yoshitaka
- Abstract
We have developed a hydrosilylation reaction of alkenes using 1,1,3,3‐tetramethyldisiloxane (TMDS) as a surrogate for Me2SiH2 in the presence of NaOMe, catalyzed by a bench‐stable nickel‐pincer complex supported by a monoanionic O,N,P‐tridentate ligand. The reaction of styrene derivatives proceeds smoothly under mild reaction conditions to provide the hydrosilylated products in high yields with high Markovnikov selectivity. This protocol shows a wide substrate scope and is compatible with a wide range of functional groups. Secondary hydrosilanes are also suitable under the present reaction conditions and furnish the desired products in high yields.
- Subjects
HYDROSILYLATION; ALKENES; STYRENE derivatives; NICKEL phosphide; FUNCTIONAL groups
- Publication
European Journal of Organic Chemistry, 2021, Vol 2021, Issue 39, p5449
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.202101177