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- Title
Straightforward Syntheses That Avoid Scrambling of meso-Substituted [28]Hexaphyrins.
- Authors
Plamont, Rémi; Balaban, Teodor Silviu; Canard, Gabriel
- Abstract
A two-step synthesis of meso-substituted [28]hexaphyrins in an aqueous medium was developed and optimized, and scrambling processes are avoided despite the use of a high acid concentration. The efficiency of this procedure relies on the nature of the starting material, and it can be extended to the straightforward preparation of unprecedented AB2C2D-[28]hexaphyrins bearing up to four different kinds of meso-appended aryl group.
- Subjects
HEXAPHYRIN; PORPHYRIN synthesis; MACROCYCLIC compound synthesis; MESO compounds; CHEMICAL synthesis
- Publication
European Journal of Organic Chemistry, 2017, Vol 2017, Issue 3, p593
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201601342