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- Title
Terpenyl Selenides: Synthesis and Application in Asymmetric Epoxidation.
- Authors
Banach, Anna; Ścianowski, Jacek; Uzarewicz‐Baig, Magdalena; Wojtczak, Andrzej
- Abstract
Synthesis of terpenyl selenides derived from limonene, menthol, caranol, and myrtanol is described. Three methodologies for the synthesis of terpenyl selenonium salts are compared. The results of selenium-mediated epoxidation through the use of isoselenocineole derived from limonene and methyl terpenyl, phenyl terpenyl, diterpenyl selenides, and selenonium salts are presented. The influence of solvent, counteranion, and diastereomeric purity of selenonium salt on the enantioselectivity of the epoxidation reaction is discussed.
- Subjects
SELENIDES; SELENIUM compounds synthesis; LIMONENE; DIASTEREOISOMERS synthesis; SALTS; EPOXIDATION
- Publication
European Journal of Organic Chemistry, 2015, Vol 2015, Issue 16, p3477
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201500211