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- Title
Cooperative Use of VCD and XRD for the Determination of Tetrahydrobenzoisoquinolines Absolute Configuration: A Reliable Proof of Memory of Chirality and.
- Authors
Mondal, Shovan; Naubron, Jean ‐ Valère; Campolo, Damien; Giorgi, Michel; Bertrand, Michéle P.; Nechab, Malek
- Abstract
ABSTRACT The absolute configurations (AC) of azaheterocylic compounds resulting from the cascade of enediynes involving only light atoms were unambiguously assigned by the joint use of vibrational circular dichroism (VCD) and copper radiation single crystal X-ray diffraction (XRD). These AC determinations proved that the of enediynes proceeded with memory of chirality and of configuration. Chirality 25:832-839, 2013. © 2013 Wiley Periodicals, Inc.
- Subjects
CHIRALITY; ENEDIYNES; VIBRATIONAL circular dichroism; X-ray diffraction; CONFIGURATIONS (Geometry); ANTINEOPLASTIC antibiotics
- Publication
Chirality, 2013, Vol 25, Issue 12, p832
- ISSN
0899-0042
- Publication type
Article
- DOI
10.1002/chir.22221