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- Title
Frontispiece: Diiron(III)-μ-Fluoro Bisporphyrins: Effect of Bridging Ligand on the Metal Spin State.
- Authors
Sil, Debangsu; Kumar, Amit; Rath, Sankar Prasad
- Abstract
Metalloporphyrins Bimetallic complexes bridged by small ligands (M ‐ X ‐ M motifs) have beEN extENsively investigated in connection to their presENce at the active site of various ENzymes, such as methane monooxygENase, ribonucleotide reductases, and tyrosinase. The unique properties of fluoro ‐ bridged complexes compared to their hydroxo analogs makes them a subject of great interest. In their Full Paper on page 11214 ff., S. P. Rath et al. describe the synthesis and characterization of a hitherto unknown family of diiron(III)–μ ‐ fluoro bisporphyrins. Although isoelectronic with μ ‐ hydroxo complexes, the μ ‐ fluoro species are quite divergENt in terms of electronic structure and properties.
- Subjects
LIGANDS (Chemistry); METAL-spinning
- Publication
Chemistry - A European Journal, 2016, Vol 22, Issue 32, pn/a
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201683262