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- Title
Defined Palladium-Phthalimidato Catalysts for Improved Oxidative Amination.
- Authors
Martínez, Claudio; Muñiz, Kilian
- Abstract
New palladium(II)-phthalimidato complexes have been synthesized, isolated, and structurally characterized. As demonstrated from over 30 examples, they constitute superior catalysts for oxidative amination reactions of alkenes with phthalimide as the nitrogen source. This work streamlines vicinal difunctionalization of alkenes and provides access to significantly improved and experimentally simplified synthetic protocols.
- Subjects
PALLADIUM; CATALYSTS; CHEMICAL inhibitors; OXIDATIVE addition; ADDITION reactions
- Publication
Chemistry - A European Journal, 2016, Vol 22, Issue 22, p7367
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201601128