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- Title
Laser Scribing for Perovskite Solar Modules of Long‐Term Stability.
- Authors
Jeong, Yujin; Kim, Yejin; Lee, Hanseul; Ko, Seoyeon; Ham, Seung Sik; Jung, Hye Ri; Choi, Jun Hwan; Kim, Won Mok; Jeong, Jeung‐hyun; Yoon, Seokhyun; Hwang, David J.; Kim, Gee Yeong
- Abstract
Although the efficiency of hybrid lead‐halide perovskite solar cells has been significantly improved, the efficiency gap between small‐area cells and large modules continues to be a considerable challenge. Laser scribing is essential for realizing high‐quality monolithic connections; however, the laser‐induced material changes and their correlation with device performance have not been yet well understood, in particular for the perovskite material systems. In this study, the effect of P3 laser processing conditions on device performance and stability is explained. The most interesting finding is an improvement in open‐circuit voltage (VOC) after aging and long‐term stability under low‐laser‐overlap conditions that avoid direct laser exposure to perovskite material system as a source of material degradation. It is found that a high‐laser‐overlap during P3 results in a lower fill factor after aging and accelerated degradation due to larger portion of perovskite directly exposed to laser during the scribing process. The increased VOC under low‐overlap conditions is attributed to the increased PbI2 formation in the P3 region. Moreover, a minimal pulse overlap is favorable for preserving long‐term device stability. Finally, a perovskite minimodule with an efficiency of 20.24% is successfully developed as a result of these findings.
- Subjects
HYBRID solar cells; SOLAR cells; PEROVSKITE; OPEN-circuit voltage; SCRIBES
- Publication
Solar RRL, 2024, Vol 8, Issue 8, p1
- ISSN
2367-198X
- Publication type
Article
- DOI
10.1002/solr.202301040