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- Title
Photophysical Properties and Single‐Molecule Magnet Behavior in Heterobimetallic 3d4 f Schiff Base Complexes.
- Authors
Chiboub Fellah, Fatima Zohra; Pointillart, Fabrice; Guizouarn, Thierry; Roisnel, Thierry; Dege, Necmi; Chiboub Fellah, Abdelghani; Hassaine, Ridha
- Abstract
Three new heterobimetallic Schiff base complexes of formula [(LZnCl)2Gd(H2O)](ZnCl4)0.5 (2), [(LZn(OH))(LZnCl)Sm(H2O)](ZnCl4)0.5 (3) and [(LZnCl0.5(OH)0.5)(LZnCl)Dy(H2O)](ZnCl4)0.5 (4) were designed from the reaction of the metallo‐ligand ZnL (1) (H2L=N, N′‐bis(3‐methoxysalicylaldiimine)‐1,3‐propylene‐2‐ol) and lanthanide salt in a ratio 1 to 1. The crystallographic structures of 2–4 were resolved by single crystal X‐ray diffraction. Light irradiation allowed the observation of a broad emission centered on the organic ligand which is exalted upon Zn(II) coordination. 1 is able to act as a metallo‐organic chromophore for the sensitization of the Sm(III) luminescence. Finally the Dy(III) derivative displayed Single‐Molecule Magnet (SMM) behavior with an opening of the hysteresis loop up to 5 K and a magnetic relaxation operating through Orbach, Raman and Quantum Tunneling of the Magnetization (QTM) at 0 Oe while under an applied magnetic field the QTM is efficiently cancelled.
- Subjects
SINGLE molecule magnets; SCHIFF bases; QUANTUM tunneling; MAGNETIC fields; MAGNETIC relaxation; NITROALDOL reactions
- Publication
European Journal of Inorganic Chemistry, 2022, Vol 2022, Issue 27, p1
- ISSN
1434-1948
- Publication type
Article
- DOI
10.1002/ejic.202200349