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- Title
Organosilanes in the synthesis of saturated heterocycles.
- Authors
Díez-Poza, Carlos; Fernández-Peña, Laura; Cherubin, Alberto; Lión-Villar, Juan; Barbero, Asunción
- Abstract
This account summarizes the studies towards the synthesis of saturated heterocycles using the chemistry of organosilanes. Two different synthetic approaches are described: a) the acid-mediated cyclization of unsaturated silyl alcohols and b) the silyl-Prins (or silyl-aza-Prins) cyclization of silylated alkenols. The effect of substitution on the selectivity of the annulation process is evaluated.
- Subjects
HETEROCYCLIC compounds; SILANOLS; ENOLS; SILYL ethers; ANNULATION
- Publication
ARKIVOC: Online Journal of Organic Chemistry, 2020, Vol 2020, p96
- ISSN
1551-7004
- Publication type
Article
- DOI
10.24820/ark.5550190.p011.111