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- Title
Cycloaminomethylation of dihydric phenols catalyzed by d- and f-metal compounds.
- Authors
Makhmudiyarova, N.; Kiyamutdinova, G.; Ibragimov, A.; Dzhemilev, U.
- Abstract
An efficient method has been developed for the synthesis of 7,16,25-triaryl-7,8,16,17,25,26-hexahydro-6 H,15 H,24 H-tribenzo[ f, m, t][1,5,8,12,15,19,3,10,17]hexaoxatriazacyclohenicosines, 3,8-diaryl-2,3,4,7,8,9-hexahydrobenzo[1,2- e:4,3- e′]bis[1,3]oxazines, 3,9-bis(chlorophenyl)-3,4,9,10-tetrahydro-2 H,8 H-benzo[1,2- e:3,4- e′]bis[1,3]oxazines, and 2,9-bis(chlorophenyl)-1,2,3,8,9,10-hexahydrobenzo[1,2- e:6,5- e′]bis-[1,3]oxazines via cycloaminomethylation of pyrocatechol, resorcinol, and hydroquinone with N, N-bis(methoxymethyl) anilines in the presence of samarium catalysts.
- Subjects
ARYL group; BENZENE compound synthesis; OXAZINES; SAMARIUM compounds; CATALYSTS
- Publication
Russian Journal of Organic Chemistry, 2017, Vol 53, Issue 4, p604
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1134/S1070428017040170