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- Title
Prostanoids: LXXXVII. Synthesis of 3-Hydroxy-2-phenylsulfonyl-2-cyclopentenone and Its Ethylene Acetal.
- Authors
Ivanova, N. A.; Shangiraeva, F. G.; Miftakhov, M. S.
- Abstract
By oxidation of 3-phenylmercapto-2-chloro-4,4-ethylenedioxycyclopet-2-en-1-one with H2O2 in AcOH (or with m-ClC6H4CO3H in CH2Cl22) was obtained 2-chloro-3-phenylsulfonyl-4,4-ethylenedioxycyclopent-2-en-1-one which on reduction with NaBH4 or LiAlH4 afforded respectively 3-hydroxy-2-phenylsulfonylcyclopent-2-en-1-one and its ethyleneketal.
- Subjects
PROSTANOIDS; HYDROXIDES; KETONES; EICOSANOIC acid derivatives; OXIDES; ORGANIC compounds
- Publication
Russian Journal of Organic Chemistry, 2003, Vol 39, Issue 11, p1652
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1023/B:RUJO.0000013142.41402.19