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- Title
Synthesis and spectral properties of sandwich meso-tetramethyltetrabenzoporphyrin-phthalocyanine complexes with lutetium, erbium, yttrium, and lanthanum.
- Authors
Galanin, N. E.; Yakubov, L. A.; Shaposhnikov, G. P.
- Abstract
The reaction of phthalimide with zinc(II) propanoate gave meso-tetramethyltetrabenzoporphyrinatozinc(II) whose demetalation afforded the corresponding free base. The latter was used to synthesize complexes with lutetium, erbium, yttrium, and lanthanum. Heating of these complexes with excess phthalonitrile led to the formation of sandwich meso-tetramethyltetrabenzoporphyrin-phthalocyanine complexes. Spectral properties of the resulting compounds were studied.
- Subjects
CHEMICAL reactions; COMPLEX compounds; YTTRIUM; LANTHANUM; ERBIUM; NITRILES
- Publication
Russian Journal of Organic Chemistry, 2008, Vol 44, Issue 6, p921
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1134/S1070428008060237